公元6世纪前地中海周边地区扁壶发展脉络——兼论北朝胡风扁壶来源

最早的扁壶起源于地中海地区，从埃及的“新年瓶”到科普特人的“朝圣者瓶”，其间有着较为清晰的继承与发展序列，且两类扁壶都随着殖民、贸易或朝圣等活动辐射到地中海东部地区。公元6世纪，伴随丝绸之路的东西方交往，朝圣者瓶极有可能传播到了中原地区。中原工匠选取当时流行的胡人乐舞为主题，结合中国传统扁壶与佛教造像的装饰细节，创新出了用于陪葬的精美胡风扁壶。     

TBP-TEVA萃取色层分离-α能谱法测定辐照镎靶溶解液中痕量236Pu的可行性

²³⁶Pu的含量控制是钚热源的一项重要参数，通过α能谱准确测量镎靶溶解液中痕量²³⁶Pu，建立镎靶辐照靶件溶解液中钚的分离方法。根据杂质组成特点采用TBP-TEVA萃取色层双柱分离，用氨基磺酸亚铁以及亚硝酸钠对钚进行调价，对靶件溶解液中的Al、Fe、U、Th和Np等进行分离，去污系数均大于10⁴，钚的回收率为90.7%。研究大量²³⁸Pu对α能谱测定²³⁶Pu的干扰，结果表明，大量²³⁸Pu会造成仪器本底升高，²³⁸Pu能谱峰分辨率降低；在7 500 Bq ²³⁸Pu干扰下，测量4.3 h 时，²³⁶Pu的最小可检测活度为1.20×10^-2 Bq（当量质量为6.11×10^-16 g）。计算结果表明，镎靶溶解液样品中钚的同位素比值n(²³⁶Pu)/n(²³⁸Pu) ≥4.63×10^-8时，取合适的样品量使得电沉积源中²³⁸Pu 活度在 450~7 500 Bq范围内，均可测量其中的痕量²³⁶Pu，同时可准确测定同位素比值n(²³⁶Pu)/n(²³⁸Pu)。     

Joining of dense Si3N4 ceramics with tape cast Lu-Al-Si-O-N interlayer

Lu-Al-Si-O-N tapes with different thickness were used to join gas pressure sintered Si₃N₄ ceramics. The microstructure of the joints and the influences of the joint thickness and joining temperature on the bonding strength of the as-joined Si₃N₄ ceramics have been investigated. The highest bonding strength about ~ 300 MPa of the joined specimens was achieved by using 450 µm interlayer at 1450 °C. The existence of Si₃N₄ nanowires was beneficial for the improvement of the bonding strength by interweaving the oxynitride glass matrix in the joint region.     

基于机器视觉的玻璃缺陷检测

随着科学技术的进步,高端显示屏产品对平板玻璃的质量要求越来越高,玻璃的表面缺陷检测技术也因此备受关注。传统的人眼检测方法工作量大且准确率低,已经无法满足生产实际要求。研究了一种基于机器视觉的玻璃质量检测系统,采用先进的CCD成像技术和背光式照明获取图像,用MATLAB图像处理工具箱对采集到的图像进行灰度值化、滤波降噪和阈值分割处理,实现对缺陷区域的特征提取和识别。最后用BP神经网络对玻璃表面的三种缺陷进行分类,该神经网络识别的平均误差率为9.84%,表明此检测方法具有一定的应用价值。     

鑫达黄金矿业急倾斜薄矿体中深孔采矿方法的研究与优化

近年来，随着开采技术的发展，急倾斜薄矿脉采用中深孔采矿越来越多。为了降低生产成本，提高经济效益和安全系数。通过在矿房对扇形中深孔和平行中深孔进行现场试验，得到扇形中深孔比平行中深孔工程量少、千吨采切比小的结论。将扇形中深孔采矿方法在急倾斜薄矿脉中进行推广应用，取得了一定经济效益。     

铱磷光配合物Ir(dfppy)2(phbudio)的合成及表征

以氯桥二聚体[Ir(dfppy)2(μ-Cl2)]2、1-苯基-1,3-丁二酮为原料合成了一种铱磷光配合物Ir(dfppy)2(phbudio)，产率86.0%，并通过元素分析、核磁共振谱、质谱和红外光谱表征确认了目标产物的化学结构。通过紫外-可见吸收以及荧光光谱对其光物理性质进行测试，其常温最大发射位于522 nm处，显示发射强烈的绿光，初步推测该铱磷光配合物发射可能来自金属铱到环金属配体和辅助配体的电荷转移(MLCT)跃迁。     

Improved thermal conductivity of β-Si3N4 ceramics by lowering SiO2/Y2O3 ratio using YH2 as sintering additive

A two-step sintering process was conducted to produce β-Si₃N₄ ceramics with high thermal conductivity. During the first step, native SiO₂ was eliminated, and Y₂O₃ was in situ generated by a metal hydride reduction process, resulting in a high Y₂O₃/SiO₂ ratio. The substitution YH₂ for Y₂O₃ endow Si₃N₄ ceramics with an increase of 29% in thermal conductivity from 95.3 to 123 W m⁻¹ K⁻¹ after sintered at 1900°C for 12 hours despite an inferior sinterability. This was primarily attributed to the purified enlarged grains, devitrified grain boundary phase, and reduced lattice oxygen content in the YH₂-MgO-doped material.     

变压器套管受潮缺陷分析

高压套管作为变压器重要构件,将绕组引出连接到电网,对绕组引出线起固定和绝缘作用。由于厂家生产工艺参差不齐,套管故障逐年增加,严重威胁变压器的安全运行。针对一起变压器套管受潮问题,利用油色谱、高压试验、解体等技术手段分析,认为套管受潮是将军帽密封不严从而潮气进入所致,提出严把出厂关、加强变压器套管带电测试整改措施,对预防同类型的事故有一定的借鉴意义。     

Efficient MOF- derived V–Ni3S2 nanosheet arrays for electrocatalytic overall water splitting in alkali

The synergistic achievement of low-cost earth-abundant electrocatalysts and high efficiency to meet renewable energy need is highly desirable yet challenging. Here, we developed a simple Ni foam self -templating route for V-doped Ni₃S₂ nanosheet arrays through in situ formation of metal-organic frameworks (MOFs) combined with subsequent conversion. The as-prepared MOF-V-Ni₃S₂/NF catalyst delivers outstanding electrocatalytic performance in the alkaline solution, which requires low overpotentials of 118.1 mV @10 mA cm^?2 and 268 mV @10 mA cm^?2 for hydrogen evolution reaction and oxygen evolution reaction, respectively. The V-doping and MOF-derived 3D hieratical nanostructure play a vital role in the catalytic process, which provides efficient active sites and large surface areas. Furthermore, an alkaline electrolyzer was assembled with two pieces of MOF-V-Ni₃S₂/NF, which achieves efficient water splitting at 1.58 V @10 mA cm^?2. This strategy opens up new channels to synthesize MOF-based bifunctional electrocatalysts toward overall water spitting.     

一种生物滞留池砂基填料的配比方法

填料的组成及配比是生物滞留系统功能发挥的关键因素,但当前相关的配比理论和方法还不完善.建立一种以细砂为主体基质的填料配比方法,完善砂基填料配比过程,具有一定的理论和实践价值,依据生物滞留池填料承载的主要功能,阐述了排空时间和有机质含量两个关键参数的指标内涵,论述了指标的作用与功能、指标之间的相互关系及其取值范围,并基于两个指标的约束条件,提出了一种砂基填料的配比方法.基于方法构建的砂基填料生物滞留池,总体效能较好,进一步证明了配比方法的适用性.基于理论计算和试验验证探讨了有机质和渗透系数这两个关键指标的平衡问题.